• Volume 42,Issue 6,2012 Table of Contents
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    • >综述
    • Thermal Protective Materials Development and Correlative Aeroheating Testsfor MSL Entry Capsule

      2012, 42(6).

      Abstract (1640) HTML (209) PDF 0.00 Byte (0) Comment (0) Favorites

      Abstract:The brief historical retrospect on exploring Mars and successfully landing on Mars were carried out.
      The basic status and entry conditions of Mars were introduced. The Mars Science Laboratory (MSL) program, MSL
      flying to Mars and the aeroheating conditions endured when entering the Mars atmosphere were described. The thermal
      protective materials development and correlative aeroheating tests for MSL entry capsule were introduced in details.

    • Thermal Protective Materials Development for Hypersonic Vehicles in Near Space

      2012, 42(6).

      Abstract (1285) HTML (198) PDF 0.00 Byte (0) Comment (0) Favorites

      Abstract:The definition of near space and the types of vehicles in near space were simply described . The developmental
      course of hypersonic vehicles in near space in America was reviewed. The research objects and the military
      application of Falcon program were mainly introduced. The development of thermal protective materials for hypersonic
      vehicles in Falcon program was emphasized.

    • Research Progress of Fluoropolymer-Matrix Energetic Reactive Materials

      2012, 42(6).

      Abstract (1438) HTML (202) PDF 0.00 Byte (0) Comment (0) Favorites

      Abstract:The compositions, microstructures, synthsis techniques, mechanical properties as well as impact behaviors
      of fluoropolymer-matrix reactive energetic materials were sumarized in this paper. Finaly, the applications and
      prospectives of such kind of materials were discussed as well.

    • >计算材料学
    • Strength Analysis of Carbon Fiber Laminates With Pre-Embedded Metal PartUnder Unidirectional Tensile Load

      2012, 42(6).

      Abstract (1528) HTML (215) PDF 2.74 M (2113) Comment (0) Favorites

      Abstract:The analysis models of carbon fiber reinforced epoxy laminates with cylindrical and step shape preembedded
      metal part are built based on the application of embedded metal part in composite laminates. The single
      layer in the laminates is assumed as three dimensional orthotropic material. The stress analysis of the laminates with
      embedded metal part is carried out by finite element method. The distributions of material principal direction stress of
      the single layers and the von mises stress of metal part are given. The ultimate loads of the composite laminates are
      determined based on the strength criterion of maximum stress. It is shown that the initial damages of the two models
      both occur in the 90°layer, and the damage mode is matrix cracking under tension. The initial damage of the laminates
      with cylindrical embedded metal part occurs at the twelve o’clock location of the central hole border, and the
      initial damage of the laminates with step shape embedded metal part occurs at the six o’clock location of the border
      between the No. 7th layer and the pre-embedded metal part. Owing to the more discontinuous carbon fibers, the ultimate
      load of the laminates with step shape metal part is smaller than that of the laminates with cylindrical metal part
      by 18. 03%.

    • >新材料新工艺
    • Ablation Property of C/ C-Cu Composites

      2012, 42(6).

      Abstract (1599) HTML (199) PDF 0.00 Byte (0) Comment (0) Favorites

      Abstract:Using carbonzed needled PAN-based pre-oxidized fiber felts as preform,the porous C/ C frameworks
      with different densities were fabricated by chemical vapor infiltration method ( CVI) and resin impregnation ( IR)
      methods, and then C/ C-Cu composites were manufactured by gas pressure infiltration technique. In the present
      work, the ablative properties of C/ C-Cu composites were tested by H2 -O2 ablation method. The experimental results
      indicate that the linear ablation rate and the mass ablation rate of C/ C-Cu composite with the C/ C perform at 0. 99 g/
      cm3 are lower than C/ C composite (ρ =1. 9 g/ cm3 ), exhibiting excellent ablation-resistant performance. During the
      ablation test, melting copper matrix depleted a large amount of heat,droped the surface temperature and improved the
      anti-ablation performance of C/ C-Cu. For C/ C-Cu composites,the ablation mechanisms are thermal-oxidation and
      mechanical erosion.

    • Microstructure and Properties of Al-Mg-Sc and Al-Mg-Er Alloys

      2012, 42(6).

      Abstract (1027) HTML (209) PDF 4.02 M (1936) Comment (0) Favorites

      Abstract:Two Al-Mg alloys plate with 0. 10wt% Sc and 0. 25wt% Er are prepared by casting-rolling-annealing
      technology. The variation of tensile properties, corrosion properties and microstructure of the two alloys at different
      treated condition was studied. The results show that the first, during annealing two alloys have same variation rule of
      microstructure and properties, i. e. with the increase of annealing temperature, the strength decrease but the ductility
      increase. At 350℃ /1 h annealing the alloy with 0. 10wt% Sc shows strong annealing softing-resistent ability, but the
      alloy with Er become soft when the annealing temperature is higher than 280℃; at 300℃ /1 h annealing condition,
      the tensile strength,yield strength and elongation of the alloy with 0. 10wt% Sc and 0. 25wt% Er are 424 MPa,314
      MPa,18. 3% and 350 MPa,177 MPa,29. 1%, respectively. Meanwhile, the exfoliation corrosion resistance of the
      two alloys show the same variation rule, i. e. at 200℃ /1 h annealing the exfoliation corrosion resistance of the two alloys
      is the lest, then with increase of annealing temperature, the resistance increase. After 280℃ annealing for an
      hour,two alloys can get excellent exfoliation corrosion resistance. Compared with 5B70 alloy, tensile properties, corrosion
      properties and annealing softing-resistent ability of the alloy with 0. 25wt% Sc is similar to 5B70 alloy, but its
      manufacture cost decreased, which shows good developing foresight on space vehicle.

    • Study on Mechanical Properties of F-12 Fiber/ CyanateResin Matrixed Composites

      2012, 42(6).

      Abstract (1121) HTML (149) PDF 2.17 M (1870) Comment (0) Favorites

      Abstract:The NOL rings, laminates and Ф150mm standard pressure vessels of F-12 aramid fiber/ cyanate resin
      matrix composites were manufactured by pre-impregnated wind process. The mechanical properties and fracture morphology
      of F-12 aramid fiber/ cyanate composites were also studied. The results show that the interlaminar shear
      strength(ILSS) was less than 35 MPa,and vessel performance factor (PV / Wc) of Ф150 mm standard pressure vessels
      were 34. 22 km. The strength transfer rate of F-12 fiber in Ф150 mm pressure vessels was 70. 22%. The form of fracture
      surface mainly reveals tearing and fibrillation of F-12 fiber.

    • Curing Kinetics of an Eutectic Aromatic Amine/ Epoxy ResinE44 by Nonisothermal DSC Method

      2012, 42(6).

      Abstract (1572) HTML (205) PDF 1.49 M (2194) Comment (0) Favorites

      Abstract:The curing reaction kinetics of an eutectic aromatic amine/ epoxy resin E44 system is investigated by
      nonisothermal DSC method. The kinetic parameters of this system are calculated by Kissinger, Ozawa and Crane equations:
      the apparent activation energy E =49. 2 kJ/ mol(by Kissinger and Ozawa methods), the reaction order n =
      0. 95(by Crane equation), the frequent factor A =2. 60×105 s-1(by Kissinger method). The kinetic model of the curing
      process based on n order reaction equation is established, which is used for modeling the curing reaction characteristics.
      The curing conditions are defined as follow: 50℃ /2 h, 140℃ /2 h, post-curing 200℃ /2 h. The curing behavior
      of the system is hardly affected by the change in the amount of the filler boron carbide (B4C) added into the
      eutectic aromatic amine/ epoxy resin E44 system.

    • Preparation and Microwave Absorbing Properties ofPoly(o-ethoxyaniline) / Fe3 O4 Nano-Multilayer Films

      2012, 42(6).

      Abstract (1382) HTML (162) PDF 1.80 M (1857) Comment (0) Favorites

      Abstract:Poly(o-ethoxyaniline) / Fe3O4 nano-multilayer films were prepared by layer-by-layer electrostatic selfassembly.
      Poly(o-ethoxyaniline) was synthesized by chemical oxidation and Fe3O4 fluid was obtained by hydrothermal
      method. The morphologies, electromagnetic parameters and microwave absorbing properties of the film were characterized
      by means of scanning electron microscope (SEM) and vector network analyzer. The SEM picture indicated that
      the film was sheeted. The film had both magnetic loss and dielectric loss, but had magnetic loss predominantly. Besides,
      in the lower frequency range (8-10 GHz), when the thickness of the film was 3. 5 mm, microwave absorbing
      effect is better and the minimal reflection loss is -11. 5 dB. In the lower frequency range (10-12. 5 GHz), the minimal
      reflection loss is -10. 4 dB when the thickness of the film was 2. 5 mm.

    • Effect of ZrB2 on Properties of C/ C-SiC Composites

      2012, 42(6).

      Abstract (1202) HTML (185) PDF 4.66 M (2030) Comment (0) Favorites

      Abstract:Carbon fiber needling preform reinforced C/ C-SiC composites and C/ C-SiC-ZrB2 composites were
      prepared by liquor dipping process. The mechanical, thermal and ablation properties of the composites were investigated
      and compared. The results show that the flexural strength,compress strength and shear strength of the C/ C-SiCZrB2
      composite are 199 MPa, 274 MPa and 19. 3 MPa respectively. These mechanical properties of the C/ C-SiCZrB2
      composite are all lower than the counterpart properties of C/ C-SiC composite. Compared with C/ C-SiC composite,
      thermal conductivity of the C/ C-SiC-ZrB2 is greatly higher and the linear expansion coefficient of the C/ C-SiCZrB2
      composite is slightly lower. The ablation behavior of them is studied by arc wind tunnel test at a temperature of 2
      500 K for 600 s. The C/ C-SiC-ZrB2 composite has an average mass ablation rate of 0. 4×10-4 g/ s and has excellent
      properties of oxidation resistance and ablation resistance.

    • Preparation of Carbon Micro-Coils Using Ni-Fe-P Alloy as Catalyst

      2012, 42(6).

      Abstract (1515) HTML (208) PDF 6.57 M (1857) Comment (0) Favorites

      Abstract:The Ni-Fe-P alloy catalysts were deposited on the graphite matrix using electroless plating method,
      the catalysts were also characterized and analyzed by scanning electron microscopy, X-ray diffraction, energy dispersive
      X-ray. Using the heat treated Ni-Fe-P alloy as catalyst, thiophene as impurity, acetylene as the carbon source,
      the carbon micro-coils were successfully prepared by chemical vapor deposition method under the reaction temperature
      at 650℃. The study found that the resulting products are almost a regular dimension, morphology of the double helix
      carbon fibers, the length of the fiber is millimeter, the helix diameter and the single fiber diameter are 2 to 3 μm,0. 5
      to 0. 8 μm.

    • Preparation, Structure and Properties of High Density PMI Foam

      2012, 42(6).

      Abstract (1542) HTML (264) PDF 1.96 M (2889) Comment (0) Favorites

      Abstract:High density Polymethacrylimide ( PMI) foam was prepared by using methacrylic acid( MAA) and
      acrylonitrile(AN) as the main monomers. The influence of the flowing agent dosage, foaming temperature and foaming
      time on the density of PMI foam was discussed. The microstructure, mechanical performance and dielectric electrical
      properties at 10 GHz of the high-density PMI foam were studied. The results indicate that high-density PMI foam
      with the density of 150 to 450 kg/ m3 can be obtained by foaming 40 min at 170 to 180℃ with 1 to 5 phr flowing agent.
      The bubble edges and bubble walls of the high-density PMI foam gradually thickened with the increase of the
      foam density, following the decrease of the average cellular diameter. Meanwhile, the mechanical properties including
      compression strength, tensile strength was improved gradually, which was closen to the theoretically calculated values,
      and the dielectric constant and dielectric loss increased linearly at the same time.

    • Preparation and Electromagnetic Properties of Ni-Coated Multi-Wall Carbon Nanotubes

      2012, 42(6).

      Abstract (1302) HTML (211) PDF 5.57 M (2168) Comment (0) Favorites

      Abstract:After purification,sensitization, activation of multi-wall carbon nanotubes( CNTs),Ni-coated CNTs
      were produced by electroless plating. By DSC analysis,suitable heat treatment temperature is excavated,then Ni-coated
      CNTs were annealed under inert gas atmosphere. The products were characterized by transmission electron microscopy
      (TEM),energy chromatog raphy (EDS),X-ray diffraction (XRD). The results show that CNTs surface is successfully
      coated with a layer of nickel-phosphorus alloys,and Ni-coated CNTs after heat treatment is smoother and
      crystallization reaction is occurred, thereby electromagnetic performance is greatly enhanced. The test of electrical
      properties show that the conductivity of Ni-coated CNTs is 450 S/ m, and is improved to 1 400 S/ m after the heat
      treatment. The test of magnetic properties show Ni-coated CNTs before and after the heat treatment are soft magnetic
      material, the saturation magnetization is 2. 753 emu/ g before the heat treatment,and is improved to 11. 254 emu/ g after
      the heat treatment.

    • Microstructure and Mechanical Properties of Self-Reacting FrictionStir Welding of 2219 Aluminium Alloy

      2012, 42(6).

      Abstract (1405) HTML (207) PDF 5.91 M (2447) Comment (0) Favorites

      Abstract:An extensive investigation was carried out on the SR-FSW of 2219aluminium alloy with the thickness
      of 6 mm, and the weld appearances, microstructure and mechanical properties of the SR-FSW joint has been analyzed.
      The results indicated that the SR-FSW joint had excellent top and underside appearances without inner defects,
      distortion and seam thinning if the parameters were carefully chosen. Typical macrosections of the joint were slightly
      hourglass shpaed,and the width of the top and underside surface was slightly greater than the mid-thickness of the
      joint. As analyzed, the macrosection of the joint was related with the change of the SRPT, heat production and heat
      trasfer. The microstructure of the joint also consisted of nugget zone, thermal-mechanically affected zone, heat affected
      zone, and within each zone, the microstructure was the same as C-FSW joint. The SR-FSW joint and C-FSW joint
      had the similar hardness distribution with the typical “W” type, but the former had no anisotropic. The mechanical
      property shown that the tensile strength of the joint can reach 318. 3 MPa, and the ductility can get to 5. 5%. The
      fracture mechanisium of the joint was ductile fracture.

    • Molding Process of Composite Case of Solid Rocket Motor of Φ200 mm

      2012, 42(6).

      Abstract (1457) HTML (250) PDF 1.52 M (2228) Comment (0) Favorites

      Abstract:Composite chamber case of Φ200 mm solid-rocket motor was made by using the two kinds of epoxy
      resins E-51 and TDE-85, as well as molding process of hermetic and heat-resistance material and molding process of
      filament winding composites were adopted. The PV / W values of the finished Φ200 mm case are 32. 3 km. The hydrostatic
      burst test of 36 MPa show that the performances of the filament winding case of solid-rocket motor meet the design
      requirements.

    • Influence of Cutting Parameters on Cutting Forcesand Hole Exit Tear in Boring CFRP

      2012, 42(6).

      Abstract (1370) HTML (375) PDF 1.55 M (1969) Comment (0) Favorites

      Abstract:In this paper, some experiments were carried out by using PCD tool to bore carbon fiber reinforced
      plastics (CFRP) and the influence of cutting parameters on cutting force and hole exit tear factor(the ratio of tear size
      and hole diameter) was analyzed. The testing results showed that 3-D components of cutting forces increase along
      with the increasing of the cutting depth, feed rate and cutting speed. It is indicated that the raise of cutting speed results
      in the increasing of yield-stress of the material. Large corner radius causes the highest radial force, followed by
      the main cutting force and axial force;Tear factor is almost independent of cutting depth, but there is a linear positive
      correlation between the factor and feed rate. When increasing the cutting speed the value of tear factor shows a tendency
      to decrease and then kept essentially constant. Boring CFRP using PCD tool can effectively reduce tear degree of
      hole exit.

    • Research on Welding for Lead-Free BGA Process Method

      2012, 42(6).

      Abstract (1529) HTML (228) PDF 4.06 M (2800) Comment (0) Favorites

      Abstract:For the purpose of welding lead-free BGA devices, among three main welding processes, lead-free
      BGA reflow with Sn-Pb solder paste is chosen as process method. By adjusting the temperature zone reflow oven parameters
      in order to get the approach of the temperature curve, and by looking at the appearance, X-ray, dye penetrant,
      shear stress,metallographic, the conclusion can be made that lead-free BGA soldering technology with SnPb
      solder paste passes through test. The result shows that the process method of lead-free BGA reflow with SnPb solder
      paste can manage to weld lead-free BGA devices. The result shows that the method is reasonable an feasible.

    • >测试分析
    • Measurement of Poisson’ s Ratio of C/ C Compositeby Laser Holographic Interferometry

      2012, 42(6).

      Abstract (1604) HTML (243) PDF 1.31 M (2149) Comment (0) Favorites

      Abstract:In this paper,the principle and the method for the measurement of Poisson ratio of C/ C composite
      material by laser holographic interterometry are described. The result shows that this method is especially suitable for
      the measurement of C/ C composite Poisson’ s ratio. The mean value of Poisson’ s ratio of braided C/ C, needled
      punching C/ C, felted C/ C were 0. 196, 0. 183, 0. 040.

    • Effect of Thermal Vacuum Environment on Performance ofAdhesive Bonding Materials

      2012, 42(6).

      Abstract (1798) HTML (261) PDF 1016.00 K (2131) Comment (0) Favorites

      Abstract:The thermal vacuum of space condition is an important factor to cause properties degradation and outgassing
      contamination of adhesive bonding materials used in optic-electrical components. The thermal vacuum aging
      and volatile characteristic of several typical adhesive bonding materials were investigated. The change of mechanical
      properties and the source of volatile after thermal vacuum test were analyzed and discussed, and the pretreatment
      method under thermal vacuum condition were validated and analyzed. The results indicate that the soft silicone rubber
      adhesive display greater mass loss than that of harder epoxy resin and acrylic resin adhesives, and the condensation
      type silicone rubber and epoxy resin adhesives appear greater changes of modulus because of end hydroxyl group exist
      in their molecular structures. The pretreatment method under thermal vacuum condition could be used as an effective
      measure to reduce the outgassing contamination of adhesive bonding materials. The results are important for the design
      and screening of nonmetallic materials used in optic-electrical components.

    • >工程实践
    • Assembly for Large Aircraft Composite Hyperboloid Components

      2012, 42(6).

      Abstract (1239) HTML (199) PDF 1.01 M (2387) Comment (0) Favorites

      Abstract:In this paper, a method is provide to determine the tolerances of the components based on computation
      of digital model and data fitting, tolerances chain analysis on the aerodynamics edges, combining with equalized
      tool design and process control of model based design (MBD) model. Varity of digital methods, such as laser tracker
      and data fitting between MBD model and the product, is adopt to equalize the tolerances during assembling. The
      structural interference can be avoided with this technique, making the product meet the demand of the delivery specifications.
      Besides, it decreases the rates of tolerance exceeding and the cost of manufacturing. The accumulated tolerance
      of aerodynamics can be reduced to 10% of designed demands during assembling with the method.

    • Hammer Forging Process for 300M Ultra High StrengthSteel Die Forging of Landing Gear Cylinder

      2012, 42(6).

      Abstract (1525) HTML (158) PDF 1.94 M (2134) Comment (0) Favorites

      Abstract:The material flow stress model for 300M ultra high strength steel has been established by hot compression
      tests on the Gleeble-1500 thermal simulation testing machine. The hammer forging forming for 300M ultra high
      strength steel die forging of landing gear cylinder has been investigated by DEFORM 3D FEM software, the influence
      of hammer forging under different process parameters has been researched in this paper. The results show that: the die
      forging filled completely at 1 100℃ initial forging temperature after the three fires;the average stress of the forging is
      228 MPa and the average strain is 1. 51, which provides technical reference for hammer forging process.

    • Surface Roughness of High-Speed Milling TC21 Titanium Alloy

      2012, 42(6).

      Abstract (1329) HTML (204) PDF 849.06 K (1967) Comment (0) Favorites

      Abstract:Through the milling test of titanium alloy TC21, the surface roughness is measured with different cutting
      parameters. Orthogonal experimental design method is used to arrange the test and range analysis to process experimental
      data,and the effection to surface roughness caused by different cutting parameters, is analyzed. The most
      significant effect on the TC21 titanium alloy surface roughness of the factors is the feed per tooth, followed by the cutting
      depth and cutting speed,and the least important comes to cutting width. Based on the analysis of the mechanism of
      effect on surface roughness, smaller amount of feed and cutting depth ,larger cutting speed and cutting width should
      be used in processing

    • Analysis and Experiments of Color Difference on S781Coating Partition Painting

      2012, 42(6).

      Abstract (1407) HTML (178) PDF 3.20 M (1854) Comment (0) Favorites

      Abstract:In order to maintain the temperature of the reentry capsule, the S781 thermal coating is painted on
      outside wall of the reentry capsule of manned spacecraft. In the painting process, the color difference appears between
      the partition and adjacent partition. In this paper, the composition of color difference area of S781 coating is analyzed,
      and several experiments are designed with different painting temperatures, interval time and materials. The result
      reveals that the color difference is due to that the interval time of partition painting is longer than the surface drying
      time of the coating. The color difference becomes obviously with the interval time, which is more than 1 minute.
      And there are granules when the temperature is high, because the surface dries much more quickly. At last, an improved
      painting method of S781 thermal coat is proposed to control the joint color difference. The result will be helpful
      to the implement of thermal control of manned spacecraft.

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