厚壁C/ C 复合材料分区CVI 制备工艺研究

Technology of Thick鄄Wall C/ C Composites Preparedby Zoning Control CVI
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    摘要:

    以整体毡为增强体,丙烯和糠酮树脂为前驱体,采用分区CVI 法和树脂浸渍/ 固化、炭化相结合
    的工艺制备了厚壁C/ C 复合材料,用CT 机和偏光显微镜观察了材料的微观结构,并进行了热力学性能测试,
    结果与热梯度CVI 法进行了对比。研究结果表明:分区CVI 法制备的热解碳为光滑层结构,整体密度均匀,与
    热梯度CVI 工艺相比,总CVI 增密效率提高了近一半,特别是沉积后期,表现出明显的优势。同时,轴向压缩
    强度提高了28. 5%;径向压缩强度提高了33. 6%。线胀系数相当。通过研究认为,分区CVI 法能很好的提高
    材料的增密效率和增密均匀性,降低成本,且材料最终具有优异的热力学性能。

    Abstract:

    Using C3H6 and FA resin as carbon resources,the integral carbon felt reinforced thick鄄wall C/ C com鄄
    posites were prepared by combinational process of zoning control CVI and resin impregnation carbonization(PIC). The
    microstructure was observed by CT machine and PLM and thermodynamics properties are tested. In the mean time,the
    results was compared to thermal gradient CVI. The results indicate that microstructure is SL,pyrocarbon is distributed
    homogeneously in it. The efficiency of densification is increased by 50%,especially at the final densified stage,it
    show obvious goodness. Axial compressional strength are increased by 28. 4%,while radial compression strength in鄄
    creased by 33. 6%. The thermal properties kept unchanged. It can be concluded that zoning control CVI can improve
    efficiency of densification greatly and homogeneous distribution of pyrocarbon,lower cost and better thermal mechani鄄
    cal properties.

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李艳.厚壁C/ C 复合材料分区CVI 制备工艺研究[J].宇航材料工艺,2013,43(2).

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  • 在线发布日期: 2016-11-28
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