热处理温度对耐烧蚀酚醛树脂及其碳层力学性能的影响
作者:
作者单位:

航天材料及工艺研究所,先进功能复合材料技术重点实验室,北京 100076

中图分类号:

TB34

基金项目:

重点实验室基金(JCKY2023203-WDZC003)


The Effect of Heat Treatment Temperature on Mechanical Performance of Anti-ablation Phenolic Resin
Author:
Affiliation:

National Key Laboratory of Advanced Functional Composite Materials,Aerospace Research Institute of Materials &Processing Technology,Beijing 100076

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    摘要:

    针对酚醛树脂固化温度对耐烧蚀防热复合材料力学性能影响规律不清晰、树脂碳的强度随温度变化规律不清楚的问题,研究了固化温度对酚醛树脂拉伸模量和拉伸强度的影响,采用维氏显微硬度研究了热处理温度对树脂碳力学性能的影响规律。结果表明,酚醛树脂拉伸模量随固化温度升高而增大,拉伸强度随固化温度升高而趋于增大,拉伸模量最大值为5.04 GPa,拉伸强度最大值89.8 MPa,树脂的最高固化温度应不低于140 ℃;树脂碳的强度随热处理温度升高而升高,树脂碳层强度在1 100 ℃时最高,为酚醛树脂基耐烧蚀复合材料设计与制备提供了有益的指导和帮助。

    Abstract:

    In view of the unclear influence law of the curing temperature of phenolic resin on the mechanical properties of ablation-resistant thermal protection composites and the unclear strength variation law of resin carbon with temperature,the effects of curing temperature on the tensile modulus and tensile strength of phenolic resin were studied.The influence law of heat treatment temperature on the mechanical properties of resin carbon was investigated by Vickers microhardness.The results show that the tensile modulus of phenolic resin increases with the increase of curing temperature,and the tensile strength tends to increase with the increase of curing temperature.The maximum tensile modulus is 5.04 GPa,and the maximum tensile strength is 89.8 MPa.The highest curing temperature of the resin should not be lower than 140 ℃.The strength of resin carbon increases with the increase of heat treatment temperature, and the strength of resin carbon layer is the highest at 1 100 ℃.This provides beneficial guidance and assistance for the design and preparation of phenolic resin-based ablation-resistant composites.

    参考文献
    [1] AHMAD R B, MEHRDAD K, MOHAMMAD H N F, et al. Ablation and thermal degradation behaviour of a composite based on resol type phenolic resin: Process modeling and experimental[J]. Polymer, 2006, 47: 3661-3673.
    [2] CHEN Y,CHEN P,HONG C,et al.Improved ablation resistance of carbon-phenolic composites by introducing zirconium diboride particles[J]. Composites: Part B,2013, 47: 320-325.
    [3] PATTON R D, PITTMAN C U, WANG L, et al. Ablation, mechanical and thermal conductivity properties of vapor grown carbon fiber/phenolic matrix composites[J]. Composites: Part A, 2002, 33: 243-251.
    [4] SHAWN M W, BRIAN R S, DAVID M S. The development of a hybrid thermoplastic ballistic material with application to helmet, ARL-TR-3700[R]. Aberdeen Proving Ground, Army Research Laboratory, 2005: 2-10.
    [5] 李仲平. 防热复合材料发展与展望[J]. 复合材料学报, 2011, 28(2): 1-6.LI Z P.Major advancement and development trends of TPS composites[J].Acta Materiae Compositae Sinica,2011,28(2): 1-6.
    [6] KAMO N, HIGUCHI H O M, MORITA M. Condensation reactions of phenolic resins V: cure-acceleration effects of propylene carbonate[J]. Journal of Wood Science, 2004, 50(3):236-241.
    [7] HU H L,WANG W,JIANG L Q,et al.Curing mechanism of resole phenolic resin based on variable temperature FTIR spectra and thermogravimetry-mass spectrometry [J].Polymers & Polymer composites,2022,30:1-11.
    [8] LENGHAUS K,QIAO G G,SOLOMON D H.The effect of formaldehyde to phenol ratio on the curing and carbonization behaviour of resole resins[J].Polymer,2001,42:3355-3362.
    [9] HU H L,ZHANG Y,LIU L,et al.Effect of quantitative characteristic structure of resole phenolic prepolymer resin on thermal stability, pyrolysis behaviors,and ablation properties[J].Journal of Thermal Analysis and Calorimetry,2021,3: 1049-1062.
    [10] LOUIS P,DAVID V,ELLEN N.Phenolic Resins:A Century of Progress[M]. New York: Springer, 2010: 109-112.
    [11] 赵毓梅.酚醛树脂炭的合成及其力学性能研究[J]. 航空工程进展, 2015, 6(2):201-204.ZHAO Y M.Synthesis and mechanical properties of phenolic-based carbon[J].Advaces in Aeronautical Science and Engineering,2015,6(2):201-204.
    [12] 唐艳茹,许庆明,顾健,等.甲基酚醛树脂的制备与表征[J].长春理工大学学报(自然科学版),2021,44(1):124-127.TANG Y,XU Q,GU J,et al.Preparation and characterization of methyl phenolic resin[J].Journal of Changchun University of Science and Technology (Natural Science Edition),2021, 44(1):124-127.
    [13] 于悦,陈晓陆,谷晓飞,等.高残炭率酚醛树脂的合成及力学性能研究[J].化工新型材,2022,50(4):116-120.YU Y,CHEN X L,GU X F,et al. Synthesis and mechanical property of PF with high residual carbon rati[J].New Chemical Materials,2022, 50(4):116-120.
    [14] 张莹, 胡宏林, 王在铎,等. 基于变温红外的苯基苯酚改性酚醛树脂固化机理研究[J].复合材料科学与工程, 2021(5):37-42.ZHANG Y,HU H L,WANG Z D, et al. Curing mechanism of phenolic resin modified by phenyl phenol based on variable temperature FTIR spectra[J]. Composites Science and Engineering, 2021(5):37-42.
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张犇,胡宏林,牛光明,张博雅,朱世鹏.热处理温度对耐烧蚀酚醛树脂及其碳层力学性能的影响[J].宇航材料工艺,2025,55(1):103-107.

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  • 收稿日期:2024-06-27
  • 最后修改日期:2025-02-13
  • 录用日期:2024-12-17
  • 在线发布日期: 2025-03-04
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《宇航材料工艺》2025年青年编委招募启事

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