聚铝硅氮烷的合成、纺丝及陶瓷化性能研究
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浙江理工大学材料科学与工程学院先进陶瓷材料与纤维研究所,杭州 310018

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TB34

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国家自然科学基金面上项目 (51872262)


Study on Synthesis,Spinning and Ceramic Properties of Polyaluminosilazane
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Institute of Advanced Ceramic Materials & Fibers,School of Materials Science and Engineering,Zhejiang Sci-Tech University,Hangzhou 310018

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    摘要:

    以不同比例的聚硅氮烷液态低聚物和乙酰丙酮铝[0.1%~1%(w)]为原料,通过热聚合反应制备了一系列聚铝硅氮烷(PASZ)先驱体。PASZ经熔融纺丝、空气预氧化处理和高温裂解后得到连续SiAlCN(O)纤维。采用FT-IR、GPC、SEM、XRD和金相显微镜等测试手段对PASZ和SiAlCN(O)纤维进行了分析表征。结果表明:PASZ的重均分子量Mw为7 191~11 275 g/mol,乙酰丙酮铝质量分数为0.2%制备的PASZ在熔融状态下表现为剪切变稀,纺丝性良好,可实现长达3 km的连续纺丝。SiAlCN(O)纤维为非晶型的含铝氮化硅纤维,直径为20~70 μm,较脆;纤维表面光滑,无裂纹、沟槽等明显缺陷。

    Abstract:

    A series of polyaluminosilazanes (PASZ) precursors were prepared by thermal polymerization with different proportion of polysilazanes liquid oligomers and aluminum acetylacetone [0.1%~1%(w)] as raw materials. The continuous SiAlCN(O) fibers were obtained via the melt spinning, air pre-oxidation treatment and high temperature cracking of PASZ. The PASZ and SiAlCN(O) fibers were characterized by FT-IR, GPC, SEM, XRD and metallographic microscopy. The results show that the mass average molecular weight of PASZ is from 7 191 to 11 275 g/mol, and prepared PASZ with 0.2% aluminum acetylacetone mass fraction shows shear thinning and excellent spinning property in molten state which could be continuously prepared up to 3 km. The SiAlCN(O) fiber is amorphous aluminum-containing silicon nitride fiber and the diameter of the fiber is about 20 to 70 μm, and the fiber surface is smooth, without obvious defects such as cracks and grooves.

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李海龙,陈建军.聚铝硅氮烷的合成、纺丝及陶瓷化性能研究[J].宇航材料工艺,2022,52(5):54-59.

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  • 收稿日期:2021-02-20
  • 最后修改日期:2022-08-31
  • 录用日期:2021-05-12
  • 在线发布日期: 2022-10-20
  • 出版日期:
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