环氧树脂耐电子辐照性能
DOI:
作者:
作者单位:

南通职业大学

作者简介:

通讯作者:

中图分类号:

基金项目:


Resistance of Epoxy Resins to High鄄Energy Electron Irradiation
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    研究了电子辐照对几种4,4忆-二氨基二苯甲烷固化的环氧树脂造成的破坏效应。结果表明:在
    1. 4 MeV 电子辐照时,环氧树脂会变色、失重、开裂,同时力学性能下降。实验结果表明:双酚A 二缩水甘油醚
    (DGEBA),N,N,N忆,N忆-四缩水甘油基-4,4忆-二氨基二苯甲烷( TGDDM),对氨基苯酚三缩水甘油环氧树脂
    (TGPAP),DGEBA/ TGDDM 和DGEBA/ TGPAP 共混物均能承受106 Gy 的吸收剂量。而DGEBA/ TGPAP 共混
    物,能承受107 Gy 的吸收剂量。环氧树脂抗辐照性能的次序为DGEBA/ TGPAP>DGEBA/ TGDDM>TGPAP 抑
    TGDDM>DGEBA。环氧树脂经电子辐照后压缩模量增加,表明在辐照效应中交联机理占主导,DMA 和DSC 分
    析也证实了这一点。

    Abstract:

    The damage effects of 1. 4 MeV electron irradiation on several epoxy resins cured by 4,4忆鄄diaminodi鄄
    phenyl methane were investigated. The results show that the epoxy resins are subjected to discoloration,weight loss,
    cracking and degradation of mechanical properties when exposed to high鄄energy electron irradiation. The degradation
    varies with absorbed dose and the chemical structure of epoxy resins. Evaluated from the extent of cracking and com鄄
    pressive strength reduction,all the epoxy systems studied in this work,including diglycidyl ether of bisphenol A
    (DGEBA), N,N,N忆,N忆-tetraglycidyl-4,4忆鄄diaminodiphenyl methane (TGDDM),triglycidylether of para鄄aminophe鄄
    nol (TGPAP),the DGEBA/ TGDDM and DGEBA/ TGPAP blends are tolerant to the absorbed dose of 106 Gy. Only the
    DGEBA/ TGPAP blends, which have a moderate crosslinking density,can withstand the absorbed dose of 107 Gy. The
    order of radiation resistance of the epoxy resins is revealed to be DGEBA/ TGPAP > DGEBA/ TGDDM >TGPAP抑TG鄄
    DDM>DGEBA. An increase in compressive modulus induced by irradiation implies a crosslinking mechanism domi鄄
    nates the degradation of epoxy resins,which is confirmed by the DMA and DSC measurements

    参考文献
    相似文献
    引证文献
引用本文

刘瑞霞.环氧树脂耐电子辐照性能[J].宇航材料工艺,2012,42(2).

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2016-11-28
  • 出版日期:
第十一届航天复合材料成形与加工工艺技术中心交流会 征文通知

关闭